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As an alternative, a cumulative ternary composition model has been considered in order to estimate ternary reactivity ratios using the full conversion trajectory.
The cumulative model (essentially the Skeist equation applied to terpolymerization), shown in Equation (4), relates the cumulative terpolymer composition for each monomer (. Since it is no longer valid to assume constant composition (that is, composition drift is no longer negligible), f i must be evaluated over conversion X n, according to the model in ordinary differential equation form, shown in Equation (5) (where F i values are calculated using Equation (2)).
Molar conversion and mass conversion are related using monomer molecular weights ( MW i ), as shown in Equation (6).